Perseus analyses of μελαίνῃ:

μέλαινα: fem dat sg (attic epic ionic)
μέλας (black, dark): fem dat sg (attic epic ionic)
μελαίνω (blacken, make black): pres subj mp 2nd sg
μελαίνω (blacken, make black): pres ind mp 2nd sg
μελαίνω (blacken, make black): pres subj act 3rd sg

LSJ entries

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μέλαινα

μέλαινα, ἡ,

A. v. μέλας.

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μέλᾱς

μέλας (μέλᾰς Rhian. 58, where μέγας is corrupt for μέλας) , μέλαινα, μέλᾰν; gen. μέλᾰνος, μελαίνης, μέλᾰνος, etc.; Ep. dat. μείλανι (metri gr.) Il. 24.79: Aeol. nom. μέλαις, from *μέλανς, Choerob. in Theod. 1.123, Greg.Cor.p.599 S., hence restored in Sapph. 57:—

A. black, dark: in Hom. generally, dark in colour, οἶνος Od. 5.265; μέλαν αἷμα, κῦμα, Il. 4.149, 23.693; γαῖα μέλαινα 2.699, cf. Sapph. Supp. 5.2; ὕδωρ μέλαν Αἰσήποιο Il. 2.825, cf. Od. 4.359, νηῦς μ., from its being pitched over, Il. 1.300, al.; of men, dark, swarthy, μέλανας δὲ ἀνδρικοὺς ἰδεῖν Pl. R. 474e; ἰσχυρός τις ἦν, μ. D. 21.71; τὰ μ. black marks about the ears of dogs, X. Cyn. 5.23.

II. dark, murky, ἕσπερος Od. 1.423; εὐφρόνα Pi. N. 7.3.

2. of the voice, indistinct, Arist. Top. 106a25, Philostr. VA 4.44; βραχὺ καὶ μ. φώνημα, of Nero, D.C. 61.20.

3. dark, obscure, enigmatical, ἱστορίη AP 11.347 (Phil.).

4. of character, dark, malignant, μ. φρήν, καρδία, Sol. 42.4, Pi. Fr. 123.4; μ. ἄνθρωποι Plu. 2.12d; μ. ἦθος M. Ant.4.28.

V. μέλαινα (sc. νοῦσος), ἡ, Medic., of diseases causing black secretions (such as melaena), Hp. Morb. 2.73.

VI. μέλαν, τό, v. sub voc. (Cf. Skt. málam ‘dirt’, malinás ‘dirty’, Lett. melns ‘black’.)

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μελαίνω

μελαίνω (Act. not in Hom. or Hes.), aor. 1 inf. μελᾶναι Arist. Mete. 371a23:—Pass., pf. μεμέλαμμαι Antyll. ap. Orib. 10.36.1: aor. ἐμελάνθην S. Aj. 919; Ep. 3pl. μελάνθησαν Hes. Sc. 300: (μέλας):—

2. Medic., cause μελασμός (q. v.), Hp. Aph. 5.20:—Pass., turn black, as a symptom of mortification, Id. Art. 69, Fract. 11.

3. metaph., blacken, misrepresent, Simp. in Cael. 290.24.

4. Pass., receive an impression of blackness, S.E. M. 7.293.

II. intr., = Pass., grow black, Pl. Ti. 83a, Thphr. Ign. 50, AP 5.123 (Phld.), Plu. 2.517c.